Ionic compound having highest solubility in water
Which ionic compound has highest solubility in water? I can find CsBr having highest solubility with 1230 g/L at 25 ℃.
Note: compounds like ethanol are soluble to any extent in water, but they are covalent, not ionic.
inorganic-chemistry aqueous-solution solubility solutions liquids
add a comment |
Which ionic compound has highest solubility in water? I can find CsBr having highest solubility with 1230 g/L at 25 ℃.
Note: compounds like ethanol are soluble to any extent in water, but they are covalent, not ionic.
inorganic-chemistry aqueous-solution solubility solutions liquids
2
It would be interesting to split in the two cases of molar solubility and mass solubility, though the latter is easier to find data on directly.
– Nicolau Saker Neto
5 hours ago
add a comment |
Which ionic compound has highest solubility in water? I can find CsBr having highest solubility with 1230 g/L at 25 ℃.
Note: compounds like ethanol are soluble to any extent in water, but they are covalent, not ionic.
inorganic-chemistry aqueous-solution solubility solutions liquids
Which ionic compound has highest solubility in water? I can find CsBr having highest solubility with 1230 g/L at 25 ℃.
Note: compounds like ethanol are soluble to any extent in water, but they are covalent, not ionic.
inorganic-chemistry aqueous-solution solubility solutions liquids
inorganic-chemistry aqueous-solution solubility solutions liquids
edited 2 hours ago
andselisk
13.9k648103
13.9k648103
asked 6 hours ago
Harsh jainHarsh jain
5931514
5931514
2
It would be interesting to split in the two cases of molar solubility and mass solubility, though the latter is easier to find data on directly.
– Nicolau Saker Neto
5 hours ago
add a comment |
2
It would be interesting to split in the two cases of molar solubility and mass solubility, though the latter is easier to find data on directly.
– Nicolau Saker Neto
5 hours ago
2
2
It would be interesting to split in the two cases of molar solubility and mass solubility, though the latter is easier to find data on directly.
– Nicolau Saker Neto
5 hours ago
It would be interesting to split in the two cases of molar solubility and mass solubility, though the latter is easier to find data on directly.
– Nicolau Saker Neto
5 hours ago
add a comment |
3 Answers
3
active
oldest
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There is not going to be a single definitive answer, primarily because of a wide gray zone surrounding the domain of ionic compounds. Besides, as Nikolau noted, the question is ambiguous.
If you want mass concentration, then look at $ce{InI3}$ which claims a whopping $13100~mathrm{g/L}$. Pity that it is probably ionic in name only, judging by the solubility in non-polar solvents. Well, then look at those mentioned by andselisk, though the ionic nature of some of them is also debatable, and then at the thallium formate (a component of Clerici solution) with $sim5000~mathrm{g/L}$.
If you want molar concentration, then the question is still ambiguous (are we looking at molarity or molality?), and the pretty strong contenders are $ce{NaOH}$, $ce{BeF2}$, $ce{LiClO3}$.
So it goes.
True, $ce{InI3}$ is weird, but it's definitely not ionic and the reference for the solubility value dates back to 1940s or something:)
– andselisk
1 hour ago
add a comment |
The following data is compiled from [1, pp. 4-44, 5-167]:
Table 1. Selected solubility values of the inorganic compounds with significant ionic character at $25~mathrm{^circ C}$.
$$
begin{array}{lc}
hline
text{Formula} & text{Solubility in water}/pu{g L-1}\
hline
ce{CsF} & 5730\
ce{SbF3} & 4920\
ce{LiClO3} & 4587\
ce{Pb(ClO4)2} & 4405\
ce{ZnCl2} & 4080\
hline
end{array}
$$
Solubility of antimony(III) trichloride $ce{SbCl3}$ is $9870~mathrm{g~L^{-1}}$ at $25~mathrm{^circ C}$, but technically it's not an ionic compound.
References
- Haynes, W. M.; Lide, D. R.; Bruno, T. J. CRC Handbook of Chemistry and Physics: A Ready-Reference Book of Chemical and Physical Data.; 2017; Vol. 97.
I've seen antimony trichloride before in tables, but it is apparently very easily hydrolysed, so perhaps it shouldn't be counted either way.
– Nicolau Saker Neto
31 mins ago
@NicolauSakerNeto Yep, you are right, and the same probably goes for $ce{ZnCl2}$. I also omitted $ce{ZnBr2}$ for similar reason (and it's covalency, too).
– andselisk
29 mins ago
add a comment |
We can do better than that. Ammonium nitrate = 1500 g/L at 20°C.
add a comment |
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3 Answers
3
active
oldest
votes
3 Answers
3
active
oldest
votes
active
oldest
votes
active
oldest
votes
There is not going to be a single definitive answer, primarily because of a wide gray zone surrounding the domain of ionic compounds. Besides, as Nikolau noted, the question is ambiguous.
If you want mass concentration, then look at $ce{InI3}$ which claims a whopping $13100~mathrm{g/L}$. Pity that it is probably ionic in name only, judging by the solubility in non-polar solvents. Well, then look at those mentioned by andselisk, though the ionic nature of some of them is also debatable, and then at the thallium formate (a component of Clerici solution) with $sim5000~mathrm{g/L}$.
If you want molar concentration, then the question is still ambiguous (are we looking at molarity or molality?), and the pretty strong contenders are $ce{NaOH}$, $ce{BeF2}$, $ce{LiClO3}$.
So it goes.
True, $ce{InI3}$ is weird, but it's definitely not ionic and the reference for the solubility value dates back to 1940s or something:)
– andselisk
1 hour ago
add a comment |
There is not going to be a single definitive answer, primarily because of a wide gray zone surrounding the domain of ionic compounds. Besides, as Nikolau noted, the question is ambiguous.
If you want mass concentration, then look at $ce{InI3}$ which claims a whopping $13100~mathrm{g/L}$. Pity that it is probably ionic in name only, judging by the solubility in non-polar solvents. Well, then look at those mentioned by andselisk, though the ionic nature of some of them is also debatable, and then at the thallium formate (a component of Clerici solution) with $sim5000~mathrm{g/L}$.
If you want molar concentration, then the question is still ambiguous (are we looking at molarity or molality?), and the pretty strong contenders are $ce{NaOH}$, $ce{BeF2}$, $ce{LiClO3}$.
So it goes.
True, $ce{InI3}$ is weird, but it's definitely not ionic and the reference for the solubility value dates back to 1940s or something:)
– andselisk
1 hour ago
add a comment |
There is not going to be a single definitive answer, primarily because of a wide gray zone surrounding the domain of ionic compounds. Besides, as Nikolau noted, the question is ambiguous.
If you want mass concentration, then look at $ce{InI3}$ which claims a whopping $13100~mathrm{g/L}$. Pity that it is probably ionic in name only, judging by the solubility in non-polar solvents. Well, then look at those mentioned by andselisk, though the ionic nature of some of them is also debatable, and then at the thallium formate (a component of Clerici solution) with $sim5000~mathrm{g/L}$.
If you want molar concentration, then the question is still ambiguous (are we looking at molarity or molality?), and the pretty strong contenders are $ce{NaOH}$, $ce{BeF2}$, $ce{LiClO3}$.
So it goes.
There is not going to be a single definitive answer, primarily because of a wide gray zone surrounding the domain of ionic compounds. Besides, as Nikolau noted, the question is ambiguous.
If you want mass concentration, then look at $ce{InI3}$ which claims a whopping $13100~mathrm{g/L}$. Pity that it is probably ionic in name only, judging by the solubility in non-polar solvents. Well, then look at those mentioned by andselisk, though the ionic nature of some of them is also debatable, and then at the thallium formate (a component of Clerici solution) with $sim5000~mathrm{g/L}$.
If you want molar concentration, then the question is still ambiguous (are we looking at molarity or molality?), and the pretty strong contenders are $ce{NaOH}$, $ce{BeF2}$, $ce{LiClO3}$.
So it goes.
answered 1 hour ago
Ivan NeretinIvan Neretin
22.9k34685
22.9k34685
True, $ce{InI3}$ is weird, but it's definitely not ionic and the reference for the solubility value dates back to 1940s or something:)
– andselisk
1 hour ago
add a comment |
True, $ce{InI3}$ is weird, but it's definitely not ionic and the reference for the solubility value dates back to 1940s or something:)
– andselisk
1 hour ago
True, $ce{InI3}$ is weird, but it's definitely not ionic and the reference for the solubility value dates back to 1940s or something:)
– andselisk
1 hour ago
True, $ce{InI3}$ is weird, but it's definitely not ionic and the reference for the solubility value dates back to 1940s or something:)
– andselisk
1 hour ago
add a comment |
The following data is compiled from [1, pp. 4-44, 5-167]:
Table 1. Selected solubility values of the inorganic compounds with significant ionic character at $25~mathrm{^circ C}$.
$$
begin{array}{lc}
hline
text{Formula} & text{Solubility in water}/pu{g L-1}\
hline
ce{CsF} & 5730\
ce{SbF3} & 4920\
ce{LiClO3} & 4587\
ce{Pb(ClO4)2} & 4405\
ce{ZnCl2} & 4080\
hline
end{array}
$$
Solubility of antimony(III) trichloride $ce{SbCl3}$ is $9870~mathrm{g~L^{-1}}$ at $25~mathrm{^circ C}$, but technically it's not an ionic compound.
References
- Haynes, W. M.; Lide, D. R.; Bruno, T. J. CRC Handbook of Chemistry and Physics: A Ready-Reference Book of Chemical and Physical Data.; 2017; Vol. 97.
I've seen antimony trichloride before in tables, but it is apparently very easily hydrolysed, so perhaps it shouldn't be counted either way.
– Nicolau Saker Neto
31 mins ago
@NicolauSakerNeto Yep, you are right, and the same probably goes for $ce{ZnCl2}$. I also omitted $ce{ZnBr2}$ for similar reason (and it's covalency, too).
– andselisk
29 mins ago
add a comment |
The following data is compiled from [1, pp. 4-44, 5-167]:
Table 1. Selected solubility values of the inorganic compounds with significant ionic character at $25~mathrm{^circ C}$.
$$
begin{array}{lc}
hline
text{Formula} & text{Solubility in water}/pu{g L-1}\
hline
ce{CsF} & 5730\
ce{SbF3} & 4920\
ce{LiClO3} & 4587\
ce{Pb(ClO4)2} & 4405\
ce{ZnCl2} & 4080\
hline
end{array}
$$
Solubility of antimony(III) trichloride $ce{SbCl3}$ is $9870~mathrm{g~L^{-1}}$ at $25~mathrm{^circ C}$, but technically it's not an ionic compound.
References
- Haynes, W. M.; Lide, D. R.; Bruno, T. J. CRC Handbook of Chemistry and Physics: A Ready-Reference Book of Chemical and Physical Data.; 2017; Vol. 97.
I've seen antimony trichloride before in tables, but it is apparently very easily hydrolysed, so perhaps it shouldn't be counted either way.
– Nicolau Saker Neto
31 mins ago
@NicolauSakerNeto Yep, you are right, and the same probably goes for $ce{ZnCl2}$. I also omitted $ce{ZnBr2}$ for similar reason (and it's covalency, too).
– andselisk
29 mins ago
add a comment |
The following data is compiled from [1, pp. 4-44, 5-167]:
Table 1. Selected solubility values of the inorganic compounds with significant ionic character at $25~mathrm{^circ C}$.
$$
begin{array}{lc}
hline
text{Formula} & text{Solubility in water}/pu{g L-1}\
hline
ce{CsF} & 5730\
ce{SbF3} & 4920\
ce{LiClO3} & 4587\
ce{Pb(ClO4)2} & 4405\
ce{ZnCl2} & 4080\
hline
end{array}
$$
Solubility of antimony(III) trichloride $ce{SbCl3}$ is $9870~mathrm{g~L^{-1}}$ at $25~mathrm{^circ C}$, but technically it's not an ionic compound.
References
- Haynes, W. M.; Lide, D. R.; Bruno, T. J. CRC Handbook of Chemistry and Physics: A Ready-Reference Book of Chemical and Physical Data.; 2017; Vol. 97.
The following data is compiled from [1, pp. 4-44, 5-167]:
Table 1. Selected solubility values of the inorganic compounds with significant ionic character at $25~mathrm{^circ C}$.
$$
begin{array}{lc}
hline
text{Formula} & text{Solubility in water}/pu{g L-1}\
hline
ce{CsF} & 5730\
ce{SbF3} & 4920\
ce{LiClO3} & 4587\
ce{Pb(ClO4)2} & 4405\
ce{ZnCl2} & 4080\
hline
end{array}
$$
Solubility of antimony(III) trichloride $ce{SbCl3}$ is $9870~mathrm{g~L^{-1}}$ at $25~mathrm{^circ C}$, but technically it's not an ionic compound.
References
- Haynes, W. M.; Lide, D. R.; Bruno, T. J. CRC Handbook of Chemistry and Physics: A Ready-Reference Book of Chemical and Physical Data.; 2017; Vol. 97.
edited 1 hour ago
answered 2 hours ago
andseliskandselisk
13.9k648103
13.9k648103
I've seen antimony trichloride before in tables, but it is apparently very easily hydrolysed, so perhaps it shouldn't be counted either way.
– Nicolau Saker Neto
31 mins ago
@NicolauSakerNeto Yep, you are right, and the same probably goes for $ce{ZnCl2}$. I also omitted $ce{ZnBr2}$ for similar reason (and it's covalency, too).
– andselisk
29 mins ago
add a comment |
I've seen antimony trichloride before in tables, but it is apparently very easily hydrolysed, so perhaps it shouldn't be counted either way.
– Nicolau Saker Neto
31 mins ago
@NicolauSakerNeto Yep, you are right, and the same probably goes for $ce{ZnCl2}$. I also omitted $ce{ZnBr2}$ for similar reason (and it's covalency, too).
– andselisk
29 mins ago
I've seen antimony trichloride before in tables, but it is apparently very easily hydrolysed, so perhaps it shouldn't be counted either way.
– Nicolau Saker Neto
31 mins ago
I've seen antimony trichloride before in tables, but it is apparently very easily hydrolysed, so perhaps it shouldn't be counted either way.
– Nicolau Saker Neto
31 mins ago
@NicolauSakerNeto Yep, you are right, and the same probably goes for $ce{ZnCl2}$. I also omitted $ce{ZnBr2}$ for similar reason (and it's covalency, too).
– andselisk
29 mins ago
@NicolauSakerNeto Yep, you are right, and the same probably goes for $ce{ZnCl2}$. I also omitted $ce{ZnBr2}$ for similar reason (and it's covalency, too).
– andselisk
29 mins ago
add a comment |
We can do better than that. Ammonium nitrate = 1500 g/L at 20°C.
add a comment |
We can do better than that. Ammonium nitrate = 1500 g/L at 20°C.
add a comment |
We can do better than that. Ammonium nitrate = 1500 g/L at 20°C.
We can do better than that. Ammonium nitrate = 1500 g/L at 20°C.
answered 5 hours ago
Oscar LanziOscar Lanzi
14.8k12646
14.8k12646
add a comment |
add a comment |
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2
It would be interesting to split in the two cases of molar solubility and mass solubility, though the latter is easier to find data on directly.
– Nicolau Saker Neto
5 hours ago